Dextrothyroxine

drug
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Also known as D-thyroxineSID11112110D-T4

Summary

Dextrothyroxine (CHEMBL559) is an approved small molecule (ATC C10AX01) targeting THRA and THRB; indicated across 2 conditions including cardiovascular disorder and down syndrome.

At a glance

  • Status: Approved (max clinical phase 4)
  • Modality: Small molecule
  • ATC class: C10AX01
  • Targets: 2 (THRA, THRB)
  • Indications: 2 conditions
  • Chemistry: 776.87 Da · C15H11I4NO4

Identifiers

Drug identity and classification

FieldValue
ChEMBL IDCHEMBL559
NameDextrothyroxine
TypeSmall molecule
Max phase4
FDA approvedno
PubChem CID8730
ChEBICHEBI:30659
ATCC10AX01
Molecular formulaC15H11I4NO4
Molecular weight776.87
InChIKeyXUIIKFGFIJCVMT-GFCCVEGCSA-N

SMILES: C1=C(C=C(C(=C1I)OC2=CC(=C(C(=C2)I)O)I)I)C[C@H](C(=O)O)N

IUPAC name: (2R)-2-amino-3-[4-(4-hydroxy-3,5-diiodophenoxy)-3,5-diiodophenyl]propanoic acid

ChEBI definition: The D-enantiomer of thyroxine.

Also known as: D-thyroxine, Dextrothyroxine, SID11112110, D-T4, DEXTROTHYROXINE, dextrothyroxine

Parent form; salt/anhydrous children: CHEMBL1200777, CHEMBL3545058

Patent coverage: 1,138 distinct patent families (3,634 SureChEMBL compound mentions), from 1 matched compound structure(s). Mentions count patents naming the compound (not distinct inventions), so promiscuous / reference molecules inflate the mention figure — families are the dedup metric.

Targets

Targets

Primary targets (GtoPdb curated mechanism): the Cancer dependency column is the DepMap CRISPR fitness signal (% of screened cell lines dependent on the target).

GeneTargetActionpAffinityCancer dependencyUniProt
THRAThyroid hormone receptor-αAgonist1.7%P10827
THRBThyroid hormone receptor-βAgonist0%P10828

Broader ChEMBL bioactivity targets: 19 (assay-derived). Sample: Fructose-bisphosphate aldolase, Prelamin-A/C, 5-hydroxytryptamine receptor 2B, Glutamate NMDA receptor, Thyroid hormone receptor beta, Glucocorticoid receptor, Thromboxane A2 receptor, Solute carrier organic anion transporter family member 1C1, Menin/Histone-lysine N-methyltransferase MLL, 5-hydroxytryptamine receptor 1A.

Bioactivity

ChEMBL activities: 12 potent at pChembl ≥ 5 of 22 total. Top 30 by potency (10 = 0.1 nM, 6 = 1 µM):

TargetpChemblTypeValueUnitActivity ID
THRB8.25Potency5.6nMCHEMBL_ACT_4015915
P181137.46IC5035nMCHEMBL_ACT_332005
LMNA7.05Potency89.1nMCHEMBL_ACT_3651302
PDE4D6.58AC50260nMCHEMBL_ACT_25185305
Q9ERB56.57Ki270nMCHEMBL_ACT_11002271
P354396.48IC50330nMCHEMBL_ACT_843353
P181135.6IC502500nMCHEMBL_ACT_332006
NTSR15.32AC504800nMCHEMBL_ACT_25189981
CYP2C95.2Potency6310nMCHEMBL_ACT_5069230
CYP2C95.2AC506310nMCHEMBL_ACT_6001614
TTR5.14IC507170nMCHEMBL_ACT_1998894
HTR1A5.09AC508200nMCHEMBL_ACT_25216003

Target pathways

Aggregated over 2 target gene(s): THRA, THRB.

Top Reactome pathways

9 total, by targets touching each:

PathwayTargetsGenes
Generic Transcription Pathway2THRA, THRB
Nuclear Receptor transcription pathway2THRA, THRB
SUMOylation of intracellular receptors2THRA, THRB
RNA Polymerase II Transcription2THRA, THRB
Gene expression (Transcription)2THRA, THRB
SUMOylation1THRB
SUMO E3 ligases SUMOylate target proteins1THRB
Metabolism of proteins1THRB
Post-translational protein modification1THRB

Dominant GO biological processes

GO termTargets
negative regulation of transcription by RNA polymerase II2
thyroid hormone receptor signaling pathway2
positive regulation of thyroid hormone receptor signaling pathway2
regulation of transcription by RNA polymerase II2
regulation of heart contraction2
female courtship behavior2
cell differentiation2
mRNA transcription by RNA polymerase II2
negative regulation of DNA-templated transcription2
positive regulation of transcription by RNA polymerase II2
retinoic acid receptor signaling pathway2
type I pneumocyte differentiation2
regulation of DNA-templated transcription2
animal organ morphogenesis2
intracellular receptor signaling pathway2

Indications & clinical

Indications

2 indications (1 at ChEMBL trial phase 4). Phase below is the highest clinical-trial phase recorded for this drug against each disease — not the molecule’s overall approval status (that is in the Summary).

IndicationTrial phaseMONDOEFO
cardiovascular disorder4MONDO:0004995EFO:0000319
Down syndrome3MONDO:0008608EFO:0001064

Clinical trials

Total trials: 0.

Clinical evidence (CIViC)

No CIViC predictive evidence (expected for non-precision-medicine drugs).

Pharmacology

Pharmacogenomics

No CPIC/DPWG dosing guideline or drug-level clinical/variant annotations in PharmGKB for this molecule.

Molecules sharing ≥1 of this drug’s curated primary targets, merged from two biobtree sources and ranked by shared-target count, then clinical phase: ChEMBL clinical-stage candidates (development phase ≥2) and PubChem drug-class bioactivity (approved / known drugs acting on the target). Deduplicated by drug name; the drug’s own salt forms are excluded. Note: for a drug with few primary targets a shared-target match can reflect off-target / promiscuous binding rather than the same therapeutic mechanism — the phase ordering surfaces bona-fide therapeutics first.

112 molecules share ≥1 primary target. Top 60 by shared-target count:

MoleculeSourceStatusShared targets
AMIODARONEChEMBL + PubChemPhase 4 (approved)THRA, THRB
LIOTHYRONINEChEMBL + PubChemPhase 4 (approved)THRA, THRB
RESMETIROMChEMBL + PubChemPhase 4 (approved)THRA, THRB
LEVOTHYROXINEChEMBLPhase 4 (approved)THRA, THRB
ROXADUSTATChEMBLPhase 4 (approved)THRA, THRB
EPROTIROMEChEMBLPhase 3THRA, THRB
TIRATRICOLChEMBLPhase 3THRA, THRB
AXITIROMEChEMBLPhase 2THRA, THRB
DETROTHYRONINEChEMBLPhase 2THRA, THRB
MB07811ChEMBLPhase 2THRA, THRB
SOBETIROMEChEMBLPhase 2THRA, THRB
THYROPROPIC ACIDChEMBLPhase 2THRA, THRB
ACETAZOLAMIDEChEMBLPhase 4 (approved)THRB
ACETOHEXAMIDEChEMBLPhase 4 (approved)THRB
ACETYLCYSTEINEChEMBLPhase 4 (approved)THRB
ALTRETAMINEChEMBLPhase 4 (approved)THRB
AMANTADINEChEMBLPhase 4 (approved)THRB
AMILORIDEChEMBLPhase 4 (approved)THRB
AMINOCAPROIC ACIDChEMBLPhase 4 (approved)THRB
AMINOPYRINEChEMBLPhase 4 (approved)THRB
AMOXAPINEChEMBLPhase 4 (approved)THRB
ATORVASTATINChEMBLPhase 4 (approved)THRB
AZARIBINEChEMBLPhase 4 (approved)THRB
BENZBROMARONEChEMBLPhase 4 (approved)THRB
BISOPROLOLChEMBLPhase 4 (approved)THRB
BITHIONOLChEMBLPhase 4 (approved)THRB
CARBETAPENTANEChEMBLPhase 4 (approved)THRB
CHLORMADINONEChEMBLPhase 4 (approved)THRB
CHLORMEZANONEChEMBLPhase 4 (approved)THRB
CHLORPROPAMIDEChEMBLPhase 4 (approved)THRB
CLOMIPRAMINEChEMBLPhase 4 (approved)THRB
CYCLOTHIAZIDEChEMBLPhase 4 (approved)THRB
CYTARABINEChEMBLPhase 4 (approved)THRB
DAUNORUBICINChEMBLPhase 4 (approved)THRB
DEBRISOQUINChEMBLPhase 4 (approved)THRB
DIAZOXIDEChEMBLPhase 4 (approved)THRB
DILTIAZEMChEMBLPhase 4 (approved)THRB
DIPYRIDAMOLEChEMBLPhase 4 (approved)THRB
DISOPYRAMIDEChEMBLPhase 4 (approved)THRB
DITHIAZANINE IODIDEChEMBLPhase 4 (approved)THRB
DOXORUBICINChEMBLPhase 4 (approved)THRB
DYCLONINEChEMBLPhase 4 (approved)THRB
GENTIAN VIOLETChEMBLPhase 4 (approved)THRB
HEXACHLOROPHENEChEMBLPhase 4 (approved)THRB
HYDROCHLOROTHIAZIDEChEMBLPhase 4 (approved)THRB
IDARUBICINChEMBLPhase 4 (approved)THRB
INAMRINONEChEMBLPhase 4 (approved)THRB
INDIGOTINDISULFONATEChEMBLPhase 4 (approved)THRB
ISOSORBIDEChEMBLPhase 4 (approved)THRB
ISOTRETINOINChEMBLPhase 4 (approved)THRB
LEFLUNOMIDEChEMBLPhase 4 (approved)THRB
MECLOFENAMATEChEMBLPhase 4 (approved)THRB
MESALAMINEChEMBLPhase 4 (approved)THRB
METHACYCLINEChEMBLPhase 4 (approved)THRB
METHYLENE BLUEChEMBLPhase 4 (approved)THRB
METHYLENE BLUE CATIONChEMBLPhase 4 (approved)THRB
METHYSERGIDEChEMBLPhase 4 (approved)THRB
METRONIDAZOLEChEMBLPhase 4 (approved)THRB
MOLSIDOMINEChEMBLPhase 4 (approved)THRB
OXYTETRACYCLINEChEMBLPhase 4 (approved)THRB