Edrophonium

drug
On this page

Also known as Edrophonium cationEdrophonium ionEnlon-plusSID11111143SID90341680SID11111144SID50100235SID50104222EDROPHONIUM CHLORIDE

Summary

Edrophonium (CHEMBL1104) is an approved small-molecule EC 3.1.1.8 (cholinesterase) inhibitor (ATC V04CX07) targeting ACHE; indicated across 2 conditions including orthostatic hypotension and postural orthostatic tachycardia syndrome.

At a glance

  • Status: Approved (max clinical phase 4)
  • Modality: Small molecule
  • ATC class: V04CX07
  • Targets: 1 (ACHE)
  • Indications: 2 conditions
  • Clinical trials: 1
  • Chemistry: 166.24 Da · C10H16NO+

Identifiers

Drug identity and classification

FieldValue
ChEMBL IDCHEMBL1104
NameEdrophonium
TypeSmall molecule
Max phase4
FDA approvedno
PubChem CID3202
ChEBICHEBI:251408
ATCV04CX07
Molecular formulaC10H16NO+
Molecular weight166.24
InChIKeyVWLHWLSRQJQWRG-UHFFFAOYSA-O

SMILES: CC[N+](C)(C)C1=CC(=CC=C1)O

IUPAC name: ethyl-(3-hydroxyphenyl)-dimethylazanium

ChEBI definition: A quaternary ammonium ion that is N-ethyl-N,N-dimethylanilinium in which one of the meta positions is substituted by a hydroxy group. It is a reversible inhibitor of cholinesterase, with a rapid onset (30-60 seconds after injection) but a short duration of action (5-15 minutes). The chloride salt is used in myasthenia gravis both diagnostically and to distinguish between under- or over-treatment with other anticholinesterases. It has also been used for the reversal of neuromuscular blockade in anaesthesia, and for the management of poisoning due to tetrodotoxin, a neuromuscular blocking toxin found in puffer fish and other marine animals.

Pharmacological roles (ChEBI): EC 3.1.1.8 (cholinesterase) inhibitor, diagnostic agent, antidote.

Also known as: Edrophonium, Edrophonium cation, Edrophonium ion, Enlon-plus, SID11111143, SID90341680, SID11111144, SID50100235, SID50104222, EDROPHONIUM, EDROPHONIUM CHLORIDE, edrophonium

Parent form; salt/anhydrous children: CHEMBL60745, CHEMBL1128

Patent coverage: 6,476 distinct patent families (17,617 SureChEMBL compound mentions), from 2 matched compound structure(s). One matched structure accounts for 17,615 (100%) of the total. Mentions count patents naming the compound (not distinct inventions), so promiscuous / reference molecules inflate the mention figure — families are the dedup metric.

Targets

Targets

Primary targets (GtoPdb curated mechanism): the Cancer dependency column is the DepMap CRISPR fitness signal (% of screened cell lines dependent on the target).

GeneTargetActionpAffinityCancer dependencyUniProt
ACHEacetylcholinesterase (Yt blood group)Inhibition6.79.6%P22303

Broader ChEMBL bioactivity targets: 4 (assay-derived). Sample: Thyrotropin receptor, Acetylcholinesterase, Mu-type opioid receptor, Muscarinic acetylcholine receptor M1.

Bioactivity

ChEMBL activities: 2 potent at pChembl ≥ 5 of 6 total. Top 30 by potency (10 = 0.1 nM, 6 = 1 µM):

TargetpChemblTypeValueUnitActivity ID
ACHE5.52AC503010nMCHEMBL_ACT_25143010
OPRM15.14AC507180nMCHEMBL_ACT_25158637

Target pathways

Aggregated over 1 target gene(s): ACHE.

Top Reactome pathways

11 total, by targets touching each:

PathwayTargetsGenes
Neurotransmitter clearance1ACHE
Transmission across Chemical Synapses1ACHE
Neuronal System1ACHE
Metabolism1ACHE
Synthesis of PC1ACHE
Glycerophospholipid biosynthesis1ACHE
Phospholipid metabolism1ACHE
Peptide hormone metabolism1ACHE
Metabolism of proteins1ACHE
Synthesis, secretion, and deacylation of Ghrelin1ACHE
Metabolism of lipids1ACHE

Dominant GO biological processes

GO termTargets
acetylcholine catabolic process in synaptic cleft1
regulation of receptor recycling1
osteoblast development1
acetylcholine catabolic process1
cell adhesion1
nervous system development1
synapse assembly1
receptor internalization1
negative regulation of synaptic transmission, cholinergic1
amyloid precursor protein metabolic process1
positive regulation of protein secretion1
retina development in camera-type eye1
acetylcholine receptor signaling pathway1
positive regulation of cold-induced thermogenesis1

Indications & clinical

Indications

2 indications (0 at ChEMBL trial phase 4). Phase below is the highest clinical-trial phase recorded for this drug against each disease — not the molecule’s overall approval status (that is in the Summary).

IndicationTrial phaseMONDOEFO
orthostatic hypotension1MONDO:0005469EFO:0005252
postural orthostatic tachycardia syndrome1MONDO:0011479EFO:1000645

Clinical trials

Total trials: 1.

Phase distribution

PhaseTrials
PHASE11

Top trials by phase / activity

NCTPhaseStatusTitle
NCT00748059PHASE1COMPLETEDThe Pathophysiology of Orthostatic Hypotension

Clinical evidence (CIViC)

No CIViC predictive evidence (expected for non-precision-medicine drugs).

Pharmacology

Pharmacogenomics

No CPIC/DPWG dosing guideline or drug-level clinical/variant annotations in PharmGKB for this molecule.

Molecules sharing ≥1 of this drug’s curated primary targets, merged from two biobtree sources and ranked by shared-target count, then clinical phase: ChEMBL clinical-stage candidates (development phase ≥2) and PubChem drug-class bioactivity (approved / known drugs acting on the target). Deduplicated by drug name; the drug’s own salt forms are excluded. Note: for a drug with few primary targets a shared-target match can reflect off-target / promiscuous binding rather than the same therapeutic mechanism — the phase ordering surfaces bona-fide therapeutics first.

152 molecules share ≥1 primary target. Top 60 by shared-target count:

MoleculeSourceStatusShared targets
GENTIAN VIOLETChEMBL + PubChemPhase 4 (approved)ACHE
PAZOPANIBChEMBL + PubChemPhase 4 (approved)ACHE
TADALAFILChEMBL + PubChemPhase 4 (approved)ACHE
ALFUZOSINChEMBLPhase 4 (approved)ACHE
ARIPIPRAZOLEChEMBLPhase 4 (approved)ACHE
BERBERINEChEMBLPhase 4 (approved)ACHE
BOSUTINIBChEMBLPhase 4 (approved)ACHE
BROMOCRIPTINEChEMBLPhase 4 (approved)ACHE
BUTENAFINEChEMBLPhase 4 (approved)ACHE
CABERGOLINEChEMBLPhase 4 (approved)ACHE
CAFFEINEChEMBLPhase 4 (approved)ACHE
CANNABIDIOLChEMBLPhase 4 (approved)ACHE
CITALOPRAMChEMBLPhase 4 (approved)ACHE
CLOTRIMAZOLEChEMBLPhase 4 (approved)ACHE
DECAMETHONIUMChEMBLPhase 4 (approved)ACHE
DECAMETHONIUM BROMIDEChEMBLPhase 4 (approved)ACHE
DEQUALINIUMChEMBLPhase 4 (approved)ACHE
DIETHYLSTILBESTROLChEMBLPhase 4 (approved)ACHE
DISULFIRAMChEMBLPhase 4 (approved)ACHE
DOFETILIDEChEMBLPhase 4 (approved)ACHE
DONEPEZILChEMBLPhase 4 (approved)ACHE
DYCLONINEChEMBLPhase 4 (approved)ACHE
EBASTINEChEMBLPhase 4 (approved)ACHE
ECONAZOLEChEMBLPhase 4 (approved)ACHE
EPIRUBICINChEMBLPhase 4 (approved)ACHE
ETHOPROPAZINEChEMBLPhase 4 (approved)ACHE
ETHYLESTRENOLChEMBLPhase 4 (approved)ACHE
FENOFIBRATEChEMBLPhase 4 (approved)ACHE
FLAVOXATEChEMBLPhase 4 (approved)ACHE
FLUOXETINEChEMBLPhase 4 (approved)ACHE
GALANTAMINEChEMBLPhase 4 (approved)ACHE
GALLAMINEChEMBLPhase 4 (approved)ACHE
HEXACHLOROPHENEChEMBLPhase 4 (approved)ACHE
HEXAFLUORENIUMChEMBLPhase 4 (approved)ACHE
ILOPERIDONEChEMBLPhase 4 (approved)ACHE
IRINOTECANChEMBLPhase 4 (approved)ACHE
ISOFLUROPHATEChEMBLPhase 4 (approved)ACHE
LEVALLORPHANChEMBLPhase 4 (approved)ACHE
LORLATINIBChEMBLPhase 4 (approved)ACHE
LURASIDONEChEMBLPhase 4 (approved)ACHE
MELPHALANChEMBLPhase 4 (approved)ACHE
MEMANTINEChEMBLPhase 4 (approved)ACHE
MEPTAZINOLChEMBLPhase 4 (approved)ACHE
METHOXSALENChEMBLPhase 4 (approved)ACHE
MICONAZOLEChEMBLPhase 4 (approved)ACHE
MINAPRINEChEMBLPhase 4 (approved)ACHE
NAFTOPIDILChEMBLPhase 4 (approved)ACHE
NEFAZODONEChEMBLPhase 4 (approved)ACHE
NEOSTIGMINEChEMBLPhase 4 (approved)ACHE
NEOSTIGMINE METHYLSULFATEChEMBLPhase 4 (approved)ACHE
NICERGOLINEChEMBLPhase 4 (approved)ACHE
NIZATIDINEChEMBLPhase 4 (approved)ACHE
ORLISTATChEMBLPhase 4 (approved)ACHE
OXICONAZOLEChEMBLPhase 4 (approved)ACHE
PALBOCICLIBChEMBLPhase 4 (approved)ACHE
PENTAMIDINEChEMBLPhase 4 (approved)ACHE
PENTOXIFYLLINEChEMBLPhase 4 (approved)ACHE
PERICIAZINEChEMBLPhase 4 (approved)ACHE
PHYSOSTIGMINEChEMBLPhase 4 (approved)ACHE
PHYSOSTIGMINE SALICYLATEChEMBLPhase 4 (approved)ACHE