Nilutamide

drug
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Also known as AnadronNilandronNilutamidaNSC-758683RU 23908RU-23908SID11111555SID11111556SID11114201SID26747174SID26752242SID50104947SID56463082SID90341288SID85231160SID104171203SID26747175SID50104948SID50104949

Summary

Nilutamide (CHEMBL1274) is an approved small-molecule antineoplastic agent (ATC L02BB02) targeting AR; indicated across 4 conditions including neoplasm and prostate adenocarcinoma; with CIViC clinical evidence for 1 variant-indication association (e.g. AR Mutation in prostate cancer).

At a glance

  • Status: Approved (max clinical phase 4)
  • Modality: Small molecule
  • ATC class: L02BB02
  • Targets: 1 (AR)
  • Indications: 4 conditions
  • Clinical trials: 10
  • Precision-oncology evidence (CIViC): 1 variant–indication association
  • Chemistry: 317.22 Da · C12H10F3N3O4

Identifiers

Drug identity and classification

FieldValue
ChEMBL IDCHEMBL1274
NameNilutamide
TypeSmall molecule
Max phase4
FDA approvedyes
PubChem CID4493
ChEBICHEBI:7573
ATCL02BB02
Molecular formulaC12H10F3N3O4
Molecular weight317.22
InChIKeyXWXYUMMDTVBTOU-UHFFFAOYSA-N

SMILES: CC1(C(=O)N(C(=O)N1)C2=CC(=C(C=C2)[N+](=O)[O-])C(F)(F)F)C

IUPAC name: 5,5-dimethyl-3-[4-nitro-3-(trifluoromethyl)phenyl]imidazolidine-2,4-dione

Pharmacological roles (ChEBI): antineoplastic agent, androgen antagonist.

Also known as: Anadron, Nilandron, Nilutamida, Nilutamide, NSC-758683, RU 23908, RU-23908, SID11111555, SID11111556, SID11114201, SID26747174, SID26752242

Patent coverage: 14,707 distinct patent families (64,154 SureChEMBL compound mentions), from 2 matched compound structure(s). One matched structure accounts for 64,013 (100%) of the total. Mentions count patents naming the compound (not distinct inventions), so promiscuous / reference molecules inflate the mention figure — families are the dedup metric.

Targets

Targets

Primary targets (GtoPdb curated mechanism): the Cancer dependency column is the DepMap CRISPR fitness signal (% of screened cell lines dependent on the target).

GeneTargetActionpAffinityCancer dependencyUniProt
ARAndrogen receptorAntagonist7.12P10275

Broader ChEMBL bioactivity targets: 20 (assay-derived). Sample: Nuclear receptor ROR-gamma, Survival motor neuron protein, Prelamin-A/C, Ras-related protein Rab-9A, Androgen receptor, Thyrotropin receptor, Progesterone receptor, Menin/Histone-lysine N-methyltransferase MLL, Muscarinic acetylcholine receptor M1, 3’,5’-cyclic-AMP phosphodiesterase 4D.

Bioactivity

ChEMBL activities: 26 potent at pChembl ≥ 5 of 46 total. Top 30 by potency (10 = 0.1 nM, 6 = 1 µM):

TargetpChemblTypeValueUnitActivity ID
P084828.8Potency1.6nMCHEMBL_ACT_4803511
AR8.05IC509nMCHEMBL_ACT_1472449
AR8.05IC509nMCHEMBL_ACT_57340
AR7.1AC5080nMCHEMBL_ACT_25203542
TSHR6.9Potency125.9nMCHEMBL_ACT_3912221
CYP2C196.9Potency125.9nMCHEMBL_ACT_4018433
CYP2C196.9AC50125.9nMCHEMBL_ACT_6056394
CYP2C196.6Potency251.2nMCHEMBL_ACT_4016258
CYP2C196.6AC50251.2nMCHEMBL_ACT_6004302
AR6.22IC50600nMCHEMBL_ACT_22453857
P152076.05AC50883nMCHEMBL_ACT_25232901
LMNA5.75Potency1778nMCHEMBL_ACT_3639870
P152075.68AC502100nMCHEMBL_ACT_25232359
CYP1A25.6AC502512nMCHEMBL_ACT_6012065
CYP1A25.5AC503162nMCHEMBL_ACT_6055369
CYP3A45.4Potency3981nMCHEMBL_ACT_4969553
CYP3A45.4Potency3981nMCHEMBL_ACT_5034853
CYP3A45.4AC503981nMCHEMBL_ACT_6057277
AR5.3IC505000nMCHEMBL_ACT_24775612
ALOX125.2Potency6310nMCHEMBL_ACT_4527154
P152075.16AC506933nMCHEMBL_ACT_25187495
NFKB15.15Potency7080nMCHEMBL_ACT_3671909
NFKB15.15Potency7080nMCHEMBL_ACT_4585191
SMN15.1Potency7943nMCHEMBL_ACT_3874023
CYP2C195.1Potency7943nMCHEMBL_ACT_4016391
P514505.05Potency8912nMCHEMBL_ACT_4818790

Target pathways

Aggregated over 1 target gene(s): AR.

Top Reactome pathways

23 total, by targets touching each:

PathwayTargetsGenes
Signal Transduction1AR
Signaling by Rho GTPases1AR
RHO GTPase Effectors1AR
Generic Transcription Pathway1AR
Cellular responses to stress1AR
SUMOylation1AR
SUMO E3 ligases SUMOylate target proteins1AR
HSP90 chaperone cycle for steroid hormone receptors (SHR) in the presence of ligand1AR
Nuclear Receptor transcription pathway1AR
Metabolism of proteins1AR
SUMOylation of intracellular receptors1AR
RHO GTPases activate PKNs1AR
Activated PKN1 stimulates transcription of AR (androgen receptor) regulated genes KLK2 and KLK31AR
Deubiquitination1AR
Ub-specific processing proteases1AR
Post-translational protein modification1AR
RNA Polymerase II Transcription1AR
Gene expression (Transcription)1AR
Transcriptional regulation by RUNX21AR
RUNX2 regulates osteoblast differentiation1AR
RUNX2 regulates bone development1AR
Cellular responses to stimuli1AR
Signaling by Rho GTPases, Miro GTPases and RHOBTB31AR

Dominant GO biological processes

GO termTargets
negative regulation of transcription by RNA polymerase II1
MAPK cascade1
in utero embryonic development1
regulation of systemic arterial blood pressure1
epithelial cell morphogenesis1
transcription by RNA polymerase II1
signal transduction1
cell-cell signaling1
spermatogenesis1
single fertilization1
positive regulation of cell population proliferation1
negative regulation of cell population proliferation1
male gonad development1
positive regulation of gene expression1
male somatic sex determination1

Indications & clinical

Indications

4 indications (4 at ChEMBL trial phase 4). Phase below is the highest clinical-trial phase recorded for this drug against each disease — not the molecule’s overall approval status (that is in the Summary).

IndicationTrial phaseMONDOEFO
neoplasm4MONDO:0005070EFO:0000616
prostate adenocarcinoma4MONDO:0005082EFO:0000673
prostate cancer4MONDO:0008315MONDO:0008315
metastatic prostate carcinoma4MONDO:0004956EFO:0000196

Clinical trials

Total trials: 10.

Phase distribution

PhaseTrials
PHASE34
PHASE24
PHASE2/PHASE31
PHASE11

Top trials by phase / activity

NCTPhaseStatusTitle
NCT03678025PHASE3RECRUITINGStandard Systemic Therapy With or Without Definitive Treatment in Treating Participants With Metastatic Prostate Cancer
NCT00002633PHASE3COMPLETEDHormone Therapy With or Without Surgery or Radiation Therapy in Treating Patients With Prostate Cancer
NCT00002855PHASE3COMPLETEDChemotherapy Plus Hormone Therapy Versus Androgen Suppression in Treating Patients With Metastatic or Unresectable Prostate Cancer
NCT00003653PHASE3COMPLETEDHormone Therapy in Treating Patients With Rising PSA Levels Following Radiation Therapy for Prostate Cancer
NCT03070886PHASE2/PHASE3COMPLETEDAntiandrogen Therapy and Radiation Therapy With or Without Docetaxel in Treating Patients With Prostate Cancer That Has Been Removed by Surgery
NCT01786265PHASE2ACTIVE_NOT_RECRUITINGFinite Androgen Ablation With or Without Abiraterone Acetate and Prednisone in Treating Patients With Recurrent Prostate Cancer
NCT00020254PHASE2COMPLETEDVaccine Therapy Plus Sargramostim and Interleukin-2 Compared With Nilutamide Alone in Treating Patients With Prostate Cancer
NCT00028769PHASE2COMPLETEDS0032, Combination Chemotherapy Plus Hormone Therapy in Treating Patients With Metastatic Prostate Cancer
NCT00918385PHASE2TERMINATEDGenomic Guided Therapy With Dasatinib or Nilutamide in Metastatic Castration-Resistant Prostate Cancer
NCT00512668PHASE1TERMINATEDHormone Therapy and Temsirolimus in Treating Patients With Relapsed Prostate Cancer

Clinical evidence (CIViC)

Variant × indication × effect (1 predictive associations from 1 curated evidence items):

VariantIndicationEffectTherapyLevelCIViC
AR MutationProstate CancerResistanceFlutamide + Cyproterone Acetate + Nilutamide + BicalutamideCIViC BEID1521

Pharmacology

Pharmacogenomics

No CPIC/DPWG dosing guideline or drug-level clinical/variant annotations in PharmGKB for this molecule.

Molecules sharing ≥1 of this drug’s curated primary targets, merged from two biobtree sources and ranked by shared-target count, then clinical phase: ChEMBL clinical-stage candidates (development phase ≥2) and PubChem drug-class bioactivity (approved / known drugs acting on the target). Deduplicated by drug name; the drug’s own salt forms are excluded. Note: for a drug with few primary targets a shared-target match can reflect off-target / promiscuous binding rather than the same therapeutic mechanism — the phase ordering surfaces bona-fide therapeutics first.

129 molecules share ≥1 primary target. Top 60 by shared-target count:

MoleculeSourceStatusShared targets
MEGESTROLChEMBL + PubChemPhase 4 (approved)AR
ABIRATERONEChEMBLPhase 4 (approved)AR
APALUTAMIDEChEMBLPhase 4 (approved)AR
ARIPIPRAZOLEChEMBLPhase 4 (approved)AR
BECLOMETHASONE DIPROPIONATEChEMBLPhase 4 (approved)AR
BETAMETHASONEChEMBLPhase 4 (approved)AR
BICALUTAMIDEChEMBLPhase 4 (approved)AR
BITHIONOLChEMBLPhase 4 (approved)AR
BROMHEXINEChEMBLPhase 4 (approved)AR
BUDESONIDEChEMBLPhase 4 (approved)AR
CHLORMADINONEChEMBLPhase 4 (approved)AR
CLARITHROMYCINChEMBLPhase 4 (approved)AR
CLASCOTERONEChEMBLPhase 4 (approved)AR
CLOCORTOLONE PIVALATEChEMBLPhase 4 (approved)AR
CLOMIPHENEChEMBLPhase 4 (approved)AR
CORTISONEChEMBLPhase 4 (approved)AR
CYCLOFENILChEMBLPhase 4 (approved)AR
DAROLUTAMIDEChEMBLPhase 4 (approved)AR
DESOGESTRELChEMBLPhase 4 (approved)AR
DESOXIMETASONEChEMBLPhase 4 (approved)AR
DEXAMETHASONEChEMBLPhase 4 (approved)AR
DIETHYLSTILBESTROLChEMBLPhase 4 (approved)AR
DIFLORASONE DIACETATEChEMBLPhase 4 (approved)AR
DORZOLAMIDEChEMBLPhase 4 (approved)AR
DROSPIRENONEChEMBLPhase 4 (approved)AR
DYDROGESTERONEChEMBLPhase 4 (approved)AR
ENZALUTAMIDEChEMBLPhase 4 (approved)AR
EPLERENONEChEMBLPhase 4 (approved)AR
ESTRADIOLChEMBLPhase 4 (approved)AR
ESTRADIOL CYPIONATEChEMBLPhase 4 (approved)AR
ESTRADIOL VALERATEChEMBLPhase 4 (approved)AR
ESTRIOLChEMBLPhase 4 (approved)AR
ESTRONEChEMBLPhase 4 (approved)AR
ETHINYL ESTRADIOLChEMBLPhase 4 (approved)AR
ETHYNODIOL DIACETATEChEMBLPhase 4 (approved)AR
ETONOGESTRELChEMBLPhase 4 (approved)AR
FLUMETHASONE PIVALATEChEMBLPhase 4 (approved)AR
FLUOCINOLONE ACETONIDEChEMBLPhase 4 (approved)AR
FLUOCINONIDEChEMBLPhase 4 (approved)AR
FLUOXYMESTERONEChEMBLPhase 4 (approved)AR
FLURANDRENOLIDEChEMBLPhase 4 (approved)AR
FLUTAMIDEChEMBLPhase 4 (approved)AR
FLUTICASONE FUROATEChEMBLPhase 4 (approved)AR
FLUTICASONE PROPIONATEChEMBLPhase 4 (approved)AR
HALCINONIDEChEMBLPhase 4 (approved)AR
HALOBETASOL PROPIONATEChEMBLPhase 4 (approved)AR
HEXACHLOROPHENEChEMBLPhase 4 (approved)AR
HEXESTROLChEMBLPhase 4 (approved)AR
HYDROCORTISONEChEMBLPhase 4 (approved)AR
INDOMETHACINChEMBLPhase 4 (approved)AR
LEVONORGESTRELChEMBLPhase 4 (approved)AR
MEDROXYPROGESTERONEChEMBLPhase 4 (approved)AR
METHYLPREDNISOLONEChEMBLPhase 4 (approved)AR
MIFEPRISTONEChEMBLPhase 4 (approved)AR
MOMETASONE FUROATEChEMBLPhase 4 (approved)AR
NOMEGESTROLChEMBLPhase 4 (approved)AR
NORETHINDRONEChEMBLPhase 4 (approved)AR
NORETHYNODRELChEMBLPhase 4 (approved)AR
OXANDROLONEChEMBLPhase 4 (approved)AR
OXICONAZOLEChEMBLPhase 4 (approved)AR