Omaveloxolone

drug
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Also known as OmaveloxolonaRTA 408RTA-408SkyclarysOMAVELOXOLONE (RTA-408)

Summary

Omaveloxolone (CHEMBL4303525) is an approved small-molecule anti-inflammatory agent (ATC N07XX25) targeting NFE2L2; indicated across 4 conditions including friedreich ataxia and breast neoplasm.

At a glance

  • Status: Approved (max clinical phase 4)
  • Modality: Small molecule
  • ATC class: N07XX25
  • Targets: 1 (NFE2L2)
  • Indications: 4 conditions
  • Clinical trials: 18
  • Chemistry: 554.7 Da · C33H44F2N2O3

Identifiers

Drug identity and classification

FieldValue
ChEMBL IDCHEMBL4303525
NameOmaveloxolone
TypeSmall molecule
Max phase4
FDA approvedyes
PubChem CID71811910
ChEBICHEBI:229661
ATCN07XX25
Molecular formulaC33H44F2N2O3
Molecular weight554.7
InChIKeyRJCWBNBKOKFWNY-IDPLTSGASA-N

SMILES: C[C@@]12CC[C@]3(CCC(C[C@H]3[C@H]1C(=O)C=C4[C@]2(CC[C@@H]5[C@@]4(C=C(C(=O)C5(C)C)C#N)C)C)(C)C)NC(=O)C(C)(F)F

IUPAC name: N-[(4aS,6aR,6bS,8aR,12aS,14aR,14bS)-11-cyano-2,2,6a,6b,9,9,12a-heptamethyl-10,14-dioxo-1,3,4,5,6,7,8,8a,14a,14b-decahydropicen-4a-yl]-2,2-difluoropropanamide

ChEBI definition: A semi-synthetic triterpenoid drug. It is an Nrf2 activator that is approved for the treatment of Friedreich’s ataxia in adults and adolescents aged 16 years and older.

Pharmacological roles (ChEBI): antioxidant, anti-inflammatory agent, cardioprotective agent, antineoplastic agent.

Also known as: Omaveloxolona, Omaveloxolone, RTA 408, RTA-408, Skyclarys, OMAVELOXOLONE, OMAVELOXOLONE (RTA-408), Omaveloxolone (RTA-408)

Patent coverage: 187 distinct patent families (527 SureChEMBL compound mentions), from 1 matched compound structure(s). Mentions count patents naming the compound (not distinct inventions), so promiscuous / reference molecules inflate the mention figure — families are the dedup metric.

Targets

Targets

Primary targets (GtoPdb curated mechanism): the Cancer dependency column is the DepMap CRISPR fitness signal (% of screened cell lines dependent on the target).

GeneTargetActionpAffinityCancer dependencyUniProt
NFE2L2nuclear factor, erythroid 2 like 2Activation12.3%Q16236

Bioactivity

No ChEMBL bioactivity rows at pChembl ≥ 5 (expected for biologics / antibodies).

Target pathways

Aggregated over 1 target gene(s): NFE2L2.

Top Reactome pathways

27 total, by targets touching each:

PathwayTargetsGenes
Disease1NFE2L2
Cellular responses to stress1NFE2L2
Metabolism of proteins1NFE2L2
Infectious disease1NFE2L2
Post-translational protein modification1NFE2L2
Neddylation1NFE2L2
Cellular responses to stimuli1NFE2L2
Potential therapeutics for SARS1NFE2L2
SARS-CoV Infections1NFE2L2
Cytoprotection by HMOX11NFE2L2
Regulation of HMOX1 expression and activity1NFE2L2
Heme signaling1NFE2L2
Cellular response to chemical stress1NFE2L2
KEAP1-NFE2L2 pathway1NFE2L2
Nuclear events mediated by NFE2L21NFE2L2
GSK3B and BTRC:CUL1-mediated-degradation of NFE2L21NFE2L2
NFE2L2 regulating TCA cycle genes1NFE2L2
NFE2L2 regulating inflammation associated genes1NFE2L2
NFE2L2 regulating anti-oxidant/detoxification enzymes1NFE2L2
NFE2L2 regulates pentose phosphate pathway genes1NFE2L2
NFE2L2 regulating tumorigenic genes1NFE2L2
NFE2L2 regulating MDR associated enzymes1NFE2L2
NFE2L2 regulating ER-stress associated genes1NFE2L2
Regulation of NFE2L2 gene expression1NFE2L2
Viral Infection Pathways1NFE2L2
Regulation of PD-L1(CD274) transcription1NFE2L2
CHD6, CHD7, CHD8, CHD9 subfamily1NFE2L2

Dominant GO biological processes

GO termTargets
response to ischemia1
regulation of transcription by RNA polymerase II1
inflammatory response1
response to oxidative stress1
gene expression1
proteasomal ubiquitin-independent protein catabolic process1
positive regulation of gene expression1
negative regulation of cardiac muscle cell apoptotic process1
positive regulation of neuron projection development1
protein ubiquitination1
positive regulation of blood coagulation1
T cell differentiation1
endoplasmic reticulum unfolded protein response1
cellular response to oxidative stress1
PERK-mediated unfolded protein response1

Indications & clinical

Indications

4 indications (1 at ChEMBL trial phase 4). Phase below is the highest clinical-trial phase recorded for this drug against each disease — not the molecule’s overall approval status (that is in the Summary).

IndicationTrial phaseMONDOEFO
Friedreich ataxia4MONDO:0100339MONDO:0100339
breast neoplasm2MONDO:0021100MONDO:0007254
melanoma1MONDO:0005105EFO:0000756
liver disorder1MONDO:0005154EFO:0001421

Clinical trials

Total trials: 18.

Phase distribution

PhaseTrials
PHASE110
Not specified4
PHASE22
PHASE31
PHASE1/PHASE21

Top trials by phase / activity

NCTPhaseStatusTitle
NCT06953583PHASE3RECRUITINGA Study to Learn More About the Effects and Long-Term Safety of BIIB141 (Omaveloxolone) in Participants With Friedreich’s Ataxia Aged 2 to 15 Years Old (BRAVE)
NCT02255422PHASE2COMPLETEDRTA 408 Capsules in Patients With Mitochondrial Myopathy - MOTOR
NCT02255435PHASE2COMPLETEDA Study to Learn About the Effects and Safety of RTA 408 (Omaveloxolone) in People Aged 16 to 40 With Friedreich’s Ataxia
NCT02259231PHASE1/PHASE2COMPLETEDRTA 408 Capsules in Patients With Melanoma - REVEAL
NCT06054893PHASE1ACTIVE_NOT_RECRUITINGA Study to Find Out How BIIB141 (Omaveloxolone) is Processed in the Body and to Learn More About Its Safety in Participants With Friedreich’s Ataxia Aged 2 to 15 Years Old
NCT02029729PHASE1COMPLETEDRTA 408 in the Treatment of Advanced Solid Tumors (NSCLC & Melanoma) - DISCOVER
NCT03664453PHASE1COMPLETEDA Pharmacokinetic Study of Omaveloxolone in Healthy Volunteers
NCT04008186PHASE1COMPLETEDA Clinical Drug-Drug Interaction (DDI) Study With Omaveloxolone
NCT05909644PHASE1COMPLETEDAn Open-label DDI Study of Omaveloxolone in Healthy Subjects
NCT05927649PHASE1COMPLETEDA TQTc Study for Omaveloxolone
NCT06612879PHASE1COMPLETEDA Study to Find Out How BIIB141 (Omaveloxolone) Moves From the Blood Into the Breastmilk of Healthy Women Who Are Breastfeeding or Pumping Milk
NCT07019064PHASE1COMPLETEDA Study to Learn How BIIB141 (Omaveloxolone) is Processed in the Body When Taken as Capsules Compared to Sprinkled on Yogurt in Healthy Adults Aged 18 to 55
NCT07149415PHASE1COMPLETEDA Study to Learn if Taking BIIB141 (Omaveloxolone) Affects How Omeprazole is Processed in the Body and About BIIB141’s Safety in Healthy Adults Aged 18 to 55
NCT07297199PHASE1COMPLETEDA Study to Learn How the Body Processes BIIB141 (Omaveloxolone) When Taken as a Capsule or as a Tablet Dissolved in Liquid, and to Learn About Its Safety in Healthy Adults Ages 18 to 55
NCT06623890Not specifiedRECRUITINGA Study to Learn More About the Long-Term Safety of BIIB141 (Omaveloxolone) in Participants With Friedreich’s Ataxia Who Are Prescribed it by Their Own Doctors
NCT06628687Not specifiedRECRUITINGA Study to Learn How BIIB141 (Omaveloxolone) Affects the Health of Participants With Friedrich’s Ataxia Who Took it During Pregnancy and/or During Breastfeeding and About the Health of Their Babies
NCT07013292Not specifiedRECRUITINGEfficacy of Omaveloxolone Treatment for Dysphagia in French Patients With Friedreich’s Ataxia
NCT03593499Not specifiedNO_LONGER_AVAILABLEExpanded Access to Omaveloxolone for Melanoma for Patients Previously Enrolled in 408-C-1401

Clinical evidence (CIViC)

No CIViC predictive evidence (expected for non-precision-medicine drugs).

Pharmacology

Pharmacogenomics

No CPIC/DPWG dosing guideline or drug-level clinical/variant annotations in PharmGKB for this molecule.

Molecules sharing ≥1 of this drug’s curated primary targets, merged from two biobtree sources and ranked by shared-target count, then clinical phase: ChEMBL clinical-stage candidates (development phase ≥2) and PubChem drug-class bioactivity (approved / known drugs acting on the target). Deduplicated by drug name; the drug’s own salt forms are excluded. Note: for a drug with few primary targets a shared-target match can reflect off-target / promiscuous binding rather than the same therapeutic mechanism — the phase ordering surfaces bona-fide therapeutics first.

13 molecules share ≥1 primary target. Top 13 by shared-target count:

MoleculeSourceStatusShared targets
DIMETHYLChEMBLPhase 4 (approved)NFE2L2
DIPYRIDAMOLEChEMBLPhase 4 (approved)NFE2L2
DOXORUBICINChEMBLPhase 4 (approved)NFE2L2
DUTASTERIDEChEMBLPhase 4 (approved)NFE2L2
KETOCONAZOLEChEMBLPhase 4 (approved)NFE2L2
TOPOTECANChEMBLPhase 4 (approved)NFE2L2
ZAFIRLUKASTChEMBLPhase 4 (approved)NFE2L2
BARDOXOLONE METHYLChEMBLPhase 3NFE2L2
CURCUMINChEMBLPhase 3NFE2L2
RESVERATROLChEMBLPhase 3NFE2L2
SULFORAPHANEChEMBLPhase 3NFE2L2
HALOFUGINONEChEMBLPhase 2NFE2L2
acetylcysteinePubChemApprovedNFE2L2